Should've added do you see it when you put spirits in, THEN do you see any darker liquid coming out.

Alright. So i went at it again this morning with the Kolibri and some 100% mineral spirits. I used clean paper towels underneath and everything coming through the segment was clear. No dirt or grime whatsoever.
BUT, even though no dirt/grime is showing, when I apply spirits to the segment slots, the typewriter mechanics seem to free up and it types well, as it should. But I know in a few days, when everything dries up, it'll be rough again, sticky.

I am really stumped...but I'll keep going and hope for some progress

There are a few possibilities:
1. Sometimes you can have sticky problematic keys that take numerous cleanings to resolve.
2. If I recall, you live in California. Many solvent formulations are banned in California. What you are using may be a completely different product, even if it is the same brand. You would have to look up the MSDS to verify. If you cannot get real (Stoddard solvent) mineral spirits in California, you may want to use denatured alcohol, lighter fluid, or a different cleaning agent; but again, those products may be different in California, as well.
3. There could be some other mechanical problem, but since you describe it as working fine before the solvent dries/evaporates, it makes me think you either have something stubborn that will take multiple cleanings, or your solvent is the problem.

No I apologize that was a typo, the "V" key is the stubborn one at the moment. Your memory is correct though, the "N" key was indeed the misaligned slug

Yes I too have considered that I may simply be using inferior solvents. Were you the one that mentioned the startex paint thinner 100% mineral spirits in another thread? I have been meaning to get some but as you mention, its not available for sale here in California.

I have had the best luck with Artists grade mineral spirits. It's 100%, but odorless...called Gamsol.

No, no burrs or anything like that. I suspected as much myself but all I could see was that white buildup that I mentioned in another post. And again, with spirits application, most of the keys free up right away.

I just HAVE to get my hands on some real stoddard solution. My brother lives in AZ I wonder if he could send me a quart or 2 in the mail...hmmmm will look into this.